A semiconductor doped with a pentavalent impurity such as phosphorus becomes

  • A. n type, with electrons as the majority carriers
  • B. p type, with holes as the majority carriers
  • C. an insulator
  • D. a conductor with no charge carriers

Explanation

A pentavalent atom has five valence electrons but only four are needed for bonding, so the fifth is loosely bound and becomes a free electron, making electrons the majority carriers. Doping with a trivalent impurity such as boron leaves a vacancy, a hole, and gives p type material. The crystal as a whole stays electrically neutral in both cases.

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