Above its optimum temperature the rate of an enzyme catalysed reaction falls sharply because the enzyme

  • A. is used up by the reaction
  • B. is denatured as its tertiary structure breaks down
  • C. becomes a substrate itself
  • D. loses its active site to the product

Explanation

Heat breaks the hydrogen bonds and other weak interactions holding the tertiary structure, so the active site loses its shape and can no longer bind the substrate. This is denaturation and it is usually irreversible, which is why the curve falls steeply rather than plateauing. Enzymes are catalysts, so they are recovered unchanged and are never used up.

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