The dipole moment of a molecule of carbon tetrachloride is zero because

  • A. the carbon to chlorine bonds are non polar
  • B. the four polar bonds are arranged symmetrically so their dipoles cancel
  • C. chlorine and carbon have the same electronegativity
  • D. the molecule is planar

Explanation

Each bond carries a substantial dipole, but the tetrahedral symmetry means the four vectors sum to zero, leaving the molecule non polar overall. Replacing one chlorine with hydrogen destroys the symmetry and gives chloroform a measurable dipole moment. Shape therefore matters as much as bond polarity in deciding whether a molecule is polar.

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