The relation between the two molar specific heats of an ideal gas is

  • A. Cp minus Cv equals R
  • B. Cp plus Cv equals R
  • C. Cp times Cv equals R
  • D. Cp equals Cv

Explanation

Mayer's relation follows directly from the first law applied to a constant pressure heating, where the extra heat needed is the work of expansion, which for one mole and a one kelvin rise is R. The ratio Cp over Cv, written gamma, is about 1.67 for a monatomic gas and 1.4 for a diatomic one. Gamma governs the speed of sound and adiabatic changes.

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