The unit cell of sodium chloride is

  • A. simple cubic
  • B. hexagonal
  • C. body centred cubic
  • D. face centred cubic

Explanation

Sodium chloride crystallises in a face centred cubic arrangement in which each sodium ion is surrounded octahedrally by six chloride ions and each chloride by six sodium ions, giving a coordination number of six for both. Caesium chloride, whose larger cation allows eight neighbours, adopts a body centred arrangement instead. The unit cell is simply the smallest repeating block from which the whole lattice can be built.

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